Search results for "Monod equation"

showing 2 items of 2 documents

Trimeprazine is enantioselectively degraded by an activated sludge in ready biodegradability test conditions

2018

[EN] A great number of available pharmaceuticals are chiral compounds. Although they are usually manufactured as racemic mixtures, they can be enantioselectively biodegraded as a result of microbial processes. In this paper, a biodegradability assay in similar conditions to those recommended in OECD tests of enantiomers of trimeprazine (a phenothiazine employed as a racemate) is carried out. Experiments were performed in batch mode using a minimal salts medium inoculated with an activated sludge (collected from a Valencian Waste Water Treatment Plant, WWTP) and supplemented with the racemate. The concentration of the enantiomers of trimeprazine were monitored by means of a chiral HPLC metho…

Environmental EngineeringTrimeprazineEnantioselectivity010501 environmental sciences01 natural scienceschemistry.chemical_compoundMonod equationCurve fittingCelluloseWaste Management and DisposalChromatography High Pressure Liquid0105 earth and related environmental sciencesWater Science and TechnologyCivil and Structural EngineeringChromatographySewageEcological ModelingBatch experiment010401 analytical chemistryBiodegradability testEnantioselective synthesisStereoisomerismAntipruriticsTrimeprazinePrecisionBiodegradationPollution0104 chemical sciencesChiral column chromatographyBiodegradation EnvironmentalActivated sludgechemistryEnantiomerWater Pollutants ChemicalWater Research
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Anticipating the impact of pitfalls in kinetic biodegradation parameter estimation from substrate depletion curves of organic pollutants

2019

[EN] Accurate and reliable estimation of kinetic parameters of pollutant biodegradation processes is essential for environmental and health risk assessment. Common biodegradation models proposed in the literature, such as the nonlinear Monod equation and its simplified versions (e.g. Michaelis-Menten-like and first-order equations), are problematic in terms of accuracy of kinetic parameters due to the parameter correlation. However, a comparison between these models in terms of accuracy and reliability, related to data imprecision, has not been performed in the literature. This task is necessary, mainly because the model selection cannot be straightforward, as shown in this work. To facilit…

010504 meteorology & atmospheric sciencesComputer scienceHealth Toxicology and Mutagenesis010501 environmental sciencesToxicology01 natural sciencesRisk AssessmentModelling depletion curveMonod equationLimit (mathematics)Reliability (statistics)0105 earth and related environmental sciencesPollutantObservational errorEstimation theoryModel selectionReproducibility of ResultsModel comparisonGeneral MedicineModels TheoreticalPollutionNonlinear systemKineticsBiodegradation EnvironmentalParameter estimationsBiodegradationEnvironmental PollutantsBiochemical engineeringPitfallsAlgorithms
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